点击次数：
影响因子：44.6
DOI码：10.1038/s41929-023-00959-8
发表刊物：nature catalysis
摘要：The use of renewable energy is central for the realization of a circular economy, which is essential for further global economic development. In this background, hydrogen storage materials play an important role. Here we propose a previously overlooked, industrially available bulk chemical (methyl formate, MF) as an efficient and practical hydrogen storage material. Utilizing appropriate catalysts, hydrogen production from MF is significantly faster than with other established chemical hydrogen carriers, such as formic acid and methanol, under very mild conditions. The optimized MF dehydrogenation system presented here is highly active (maximum turnover frequency (TOFmax) > 44,000 h−1 and turnover number > 100,000) and selective (CO undetectable). Moreover, the solvent-free MF dehydrogenation demonstrates its application potential. Here we show the dehydrogenation reaction of MF. We expect that these insights will serve as an inspiration for the development of alternative energy materials and new catalytic transformations.
合写作者：Elisabetta Alberico；Duo Wei；Xinxin Tian；Pavel Ryabchuk；Anke Spannenberg；Rauf Razzaq；Ralf Jackstell；Jonas Massa；Peter Sponholz；Haijun Jiao*；Henrik Junge*；Matthias Beller*
第一作者：Rui Sang；Zhihong Wei；Yuya Hu
通讯作者：Haijun Jiao*；Henrik Junge*；Matthias Beller*
文献类型：期刊
卷号：6
期号：6
页面范围：543-550
是否译文：否
发表时间：2023-06-22
收录刊物：SCI
发布期刊链接：https://www.nature.com/articles/s41929-023-00959-8