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影响因子：16.4
DOI码：10.1002/anie.202214706
发表刊物：Angewandte Chemie International Edition
摘要：Diesters are of fundamental importance in the chemical industry and are used for many applications, e.g. as plasticizers, surfactants, emulsifiers, and lubricants. Herein, we present a straightforward and efficient method for the selective synthesis of diesters via palladium-catalyzed direct carbonylation of di- or polyols with readily available alkenes. Key-to-success is the use of a specific palladium catalyst with the "built-in-base" ligand L16 providing esterification of all alcohols and a high n/iso ratio. The synthesized diesters were evaluated as potential plasticizers in PVC films by measuring the glass transition temperature (T-g) via differential scanning calorimetry (DSC).
合写作者：Guillaume Mollaert；Rauf Razzaq；Helfried Neumann；Henrik Junge*；Robert Franke；* Ralf Jackstell*； Bert U.W. Maes*；Matthias Beller*
第一作者：Yuya Hu；Rui Sang；Robby Vroemans
论文类型：期刊论文
通讯作者：Henrik Junge*；Robert Franke*； Ralf Jackstell*； Bert U.W. Maes*；Matthias Beller*
文献类型：期刊
卷号：62
期号：6
是否译文：否
发表时间：2023-02-01
收录刊物：SCI
发布期刊链接：https://onlinelibrary.wiley.com/doi/10.1002/anie.202214706