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影响因子：17.2
DOI码：10.1038/s41467-024-51658-2
发表刊物：NATURE COMMUNICATIONS
摘要：Liquid (organic) hydrogen carriers ([18H]-dibenzyltoluene, MeOH, formic acid, etc.) form a toolbox for the storage and transport of green hydrogen, which is crucial for the implementation of renewable energy technologies. Simple organic salts have been scarcely investigated for this purpose, despite many advantages such as low cost and minor toxicity, as well as easy handling. Here, we present a potassium formate/potassium bicarbonate hydrogen storage and release energy system, that is applicable and shows high stability (6 months). Utilizing ppm amounts of the molecularly defined Ru-5 complex, hydrogen release rates of up to 9.3 L h-1 were achieved. The same catalyst system promoted the hydrogenation of KHCO3 to HCOOK with a TON of 9650. In this way, combined hydrogen storage-release cycles can be performed for 40 times.
合写作者：Schareina, Thomas；Hu, Yuya；Leval, Alexander；Massa, Jonas；Turan, Volkan；Sponholz, Peter；Wei, Duo*；Jackstell, Ralf*；Junge, Henrik*；Beller, Matthias*
第一作者：Sang, Rui；Stein, Carolin Amber Martina
论文类型：期刊论文
通讯作者：Wei, Duo*；Jackstell, Ralf*；Junge, Henrik*；Beller, Matthias*
文献类型：期刊
卷号：15
期号：1
是否译文：否
发表时间：2024-08-23
收录刊物：SCI
发布期刊链接：https://www.nature.com/articles/s41467-024-51658-2