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影响因子：17.0
DOI码：10.1002/anie.201700317
发表刊物：ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
摘要：The development of ligands plays a key role and provides important innovations in homogeneous catalysis. In this context, we report a novel class of ferrocenyl phosphines for the alkoxycarbonylation of industrially important alkenes. A basic feature of our ligands is the combination of sterically hindered and amphoteric moieties on the P atoms, which leads to improved activity and productivity for alkoxycarbonylation reactions compared to the current industrial state-of-the-art ligand 1,2-bis((di-tert-butylphosphino)methyl)benzene). Advantageously, palladium catalysts with these novel ligands also enable such transformations without additional acid under milder reaction conditions. The practicability of the optimized ligand was demonstrated by preparation on >10 g scale and its use in palladium-catalyzed carbonylations on kilogram scale.
合写作者：Sang, Rui；Fang, Xianjie；Franke, Robert；Spannenberg, Anke；Neumann, Helfried；Jackstell, Ralf；Beller, Matthias*；
第一作者：Dong, Kaiwu
论文类型：期刊论文
通讯作者：Beller, Matthias*
文献类型：期刊
卷号：56
期号：19
页面范围：5267 - 5271
是否译文：否
发表时间：2017-05-02
收录刊物：SCI
发布期刊链接：https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201700317