点击次数：
影响因子：16.4
DOI码：10.1002/anie.201701950
发表刊物：Angewandte Chemie International Edition
摘要：A general palladium-catalyzed synthesis of linear esters directly from sec-and tert-alcohols is described. Compared to the classic Koch-Haaf reaction, which leads to branched products, this new transformation gives the corresponding linear esters in high yields and selectivity. Key for this protocol is the use of an advanced palladium catalyst system with L2 (pytbpx) as the ligand. A variety of aliphatic and benzylic alcohols can be directly used and the catalyst efficiency for the benchmark reaction is outstanding (turnover number up to 89 000).
合写作者：Jie Liu；Rauf Razzaq；Robert Frank；Ralf Jackstell；Matthias Beller*；
第一作者：Kaiwu Dong；Rui Sang
论文类型：期刊论文
通讯作者：Matthias Beller*；
文献类型：期刊
卷号：56
期号：22
页面范围：6203 - 6207
是否译文：否
发表时间：2017-05-22
收录刊物：SCI
发布期刊链接：https://onlinelibrary.wiley.com/doi/10.1002/anie.201701950