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影响因子：15.6
DOI码：10.1021/jacs.8b01123
发表刊物：Journal of the American Chemical Society
摘要：A general and selective palladium-catalyzed alkoxycarbonylation of all kinds of alkenes with formic acid (HCOOH, FA) is described. Terminal, di-, tri-, and tetra substituted including functionalized olefins are converted into linear esters with high yields and regioselectivity. Key-to-success is the use of specific palladium catalysts containing ligands with built-in base, e.g., L5. Comparison experiments demonstrate that the active catalyst system not only facilitates isomerization and carbonylation of alkenes but also promotes the selective decomposition of HCOOH to CO under mild conditions.
合写作者：Peter Kucmierczyk；Kaiwu Dong；Robert Franke；Helfried Neumann；Ralf Jackstell；Matthias Beller*；
第一作者：Rui Sang
论文类型：期刊论文
通讯作者：Matthias Beller；
一级学科：化学
文献类型：期刊
是否译文：否
发表时间：2018-04-18
收录刊物：SCI
发布期刊链接：https://pubs-acs-org-443.e1.buaa.edu.cn/doi/10.1021/jacs.8b01123