Palladium-catalyzed carbonylations of highly substituted olefins using CO-surrogates
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影响因子:4.7
DOI码:10.1039/d0qo01164a
发表刊物:Organic Chemistry Frontiers
摘要:The first active catalyst system for the carbonylation of tri- and tetra-substituted olefins with paraformaldehyde and methyl formate is described. Specifically, using 1.0 mol% Pd(OAc)2 and 4.0 mol% 1,2-bis-(tert-butylpyridylphosphino)xylene L3 in the presence of 5.0 mol% PTSA·H2O, and 0.5 mol% Pd(OAc)2 and 2.0 mol% L3 in the presence of 8.0 mol% PTSA·H2O, respectively, allowed the corresponding linear esters to be obtained in good yields and selectivities.
合写作者:Rauf Razzaq;Helfried Neumann;Ralf Jackstell;Matthias Beller*
第一作者:Rui Sang;Carolin Schneider
论文类型:期刊论文
通讯作者:Matthias Beller*
文献类型:期刊
卷号:7
期号:22
页面范围:3681-3685
是否译文:否
发表时间:2020-11-21
收录刊物:SCI
发布期刊链接:
https://pubs.rsc.org/en/content/articlelanding/2020/qo/d0qo01164a