Impact Factor:4.7

DOI number:10.1039/c4qo00160e

Journal:ORGANIC CHEMISTRY FRONTIERS

Abstract:Ozonation of methylenecyclopropanes bearing gem-disubstituted electron-withdrawing groups (EWG) gave ring-opened oxidative products in moderate to good yields. For MCPs in which EWGs are two methoxycarbonyl groups, the ozonation gave oxidative cyclization products in methanol at -78 degrees C in the presence of CuCl; for MCPs in which EWGs are one methoxycarbonyl and one trifluoromethyl group, the ozonation produced alpha-diketones in ethyl acetate (EA) at -78 degrees C.

Co-author:Tang, Xiangying；Shi, Min*

First Author:Sang, Rui

Indexed by:Journal paper

Correspondence Author:Shi, Min*

Document Type:J

Volume:1

Issue:1

Page Number:770 - 773

Translation or Not:no

Date of Publication:2015-12-02

Included Journals:SCI

Links to published journals:https://pubs.rsc.org/en/content/articlelanding/2014/qo/c4qo00160e