Impact Factor:4.7

DOI number:10.1039/d0qo01164a

Journal:Organic Chemistry Frontiers

Abstract:The first active catalyst system for the carbonylation of tri- and tetra-substituted olefins with paraformaldehyde and methyl formate is described. Specifically, using 1.0 mol% Pd(OAc)2 and 4.0 mol% 1,2-bis-(tert-butylpyridylphosphino)xylene L3 in the presence of 5.0 mol% PTSA·H2O, and 0.5 mol% Pd(OAc)2 and 2.0 mol% L3 in the presence of 8.0 mol% PTSA·H2O, respectively, allowed the corresponding linear esters to be obtained in good yields and selectivities.

Co-author:Rauf Razzaq；Helfried Neumann；Ralf Jackstell；Matthias Beller*

First Author:Rui Sang；Carolin Schneider

Indexed by:Journal paper

Correspondence Author:Matthias Beller*

Document Type:J

Volume:7

Issue:22

Page Number:3681-3685

Translation or Not:no

Date of Publication:2020-11-21

Included Journals:SCI

Links to published journals:https://pubs.rsc.org/en/content/articlelanding/2020/qo/d0qo01164a